𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Theoretical study of the mechanism of the 1,3-dipolar cycloadditions

✍ Scribed by J.M. Lluch; J. Bertrán

Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
524 KB
Volume
35
Category
Article
ISSN
0040-4020

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Theoretical study of the reaction mechan
Theoretical study of the reaction mechanism and solvent effect on the regioselectivity of 1,3-dipolar cycloaddition reaction between azide and acetylene derivatives
✍ Xi-Bo Li; Qin-Hua Song 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 109 KB 👁 2 views

## Abstract The reaction mechanism and solvent‐dependant regioselectivity of 1,3‐dipolar cycloaddition reactions between azide and acetylene derivatives have been studied using computational methods. The two possible reaction transition states were located. Geometry and NBO analysis found that the

Theoretical study of 1,3-dipolar cycload
Theoretical study of 1,3-dipolar cycloadditions of nitrone and fulminic acid with substituted ethylenes
✍ Magnuson, Eric C.; Pranata, Julianto 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 269 KB 👁 2 views

Molecular orbital calculations were performed to examine the electronic effects involved in the regioselectivity in the 1,3-dipolar cycloaddition reaction of nitrone and fulminic acid. The substituted ethylene dipolarophiles were selected to represent a range of electron-donatingrwithdrawing abiliti

1,3-Dipolar cycloaddition of diazomethan
1,3-Dipolar cycloaddition of diazomethane to chiral azlactones. Experimental and theoretical studies
✍ Carlos Cativiela; María D. Díaz-de-Villegas; JoséI. García; Ana I. Jiménez 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 460 KB

The reaction of (E)-2-phenyl-4-[(S)-2,2-dimethyl-1,3-dioxolan-4-ylmethylen]-5(4H)-oxazolone with diazomethane has been studied under a variety of reaction conditions, and the results compared with those obtained with the corresponding (Z)-isomer. The origin of the high diastereofacial selectivity in