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Theoretical study of the kinetics and mechanism of the decomposition of trifluoromethanol, trichloromethanol, and tribromomethanol in the gas phase

✍ Scribed by Katarzyna Brudnik; Dorota Wójcik-Pastuszka; Jerzy T. Jodkowski; Jerzy Leszczynski

Book ID
106239947
Publisher
Springer-Verlag
Year
2008
Tongue
English
Weight
333 KB
Volume
14
Category
Article
ISSN
1610-2940

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The decomposition kinetics of ethylsilane under shock tube conditions (P, ca. 3100 torr, T = 1080-1245 K), both in the absence and presence of silylene trapping agents (butadiene and acetylene) are reported. Arrhenius parameters under maximum butadiene inhibition are: log K(C,H,SiH,) = 15.14-64,769