Theoretical Study of the Gauche and Trans Conformers of SiH2X–CH2X, SiH2F–CH2Y and SiH2Y–CH2F (X
✍ Scribed by Benazir Bhonoah; Anusha Ghoorun; Hassan H. Abdallah; Ponnadurai Ramasami
- Publisher
- Springer US
- Year
- 2011
- Tongue
- English
- Weight
- 945 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0095-9782
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📜 SIMILAR VOLUMES
## Abstract The multiple‐channel reactions SiH~3~ + SiH~3~CH~3~ → products and SiH~3~ + SiH~2~(CH~3~)~2~ → products are investigated by direct dynamics method. The minimum energy path (MEP) is calculated at the MP2/6‐31+G(d,p) level, and energetic information is further refined by the MC‐QCISD meth
## Abstract Raman spectra of 1,3‐disilabutane (SiH~3~CH~2~SiH~2~CH~3~) as a liquid were recorded at 293 K and as a solid at 78 K. In the Raman cryostat at 78 K an amorphous phase was first formed, giving a spectrum similar to that of the liquid. After annealing to 120 K, the sample crystallized and