The synthesis and properties of (CH2F)SiH3 and related monofluoromethylsilanes
✍ Scribed by H. Bürger; P. Moritz
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 898 KB
- Volume
- 427
- Category
- Article
- ISSN
- 0022-328X
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The multiple‐channel reactions SiH~3~ + SiH~3~CH~3~ → products and SiH~3~ + SiH~2~(CH~3~)~2~ → products are investigated by direct dynamics method. The minimum energy path (MEP) is calculated at the MP2/6‐31+G(d,p) level, and energetic information is further refined by the MC‐QCISD meth
## Abstract Raman spectra of 1,3‐disilabutane (SiH~3~CH~2~SiH~2~CH~3~) as a liquid were recorded at 293 K and as a solid at 78 K. In the Raman cryostat at 78 K an amorphous phase was first formed, giving a spectrum similar to that of the liquid. After annealing to 120 K, the sample crystallized and
Combining concentrated hydriodic acid solutions of tin(II) iodide and formamidine acetate in an inert atmosphere results in the precipitation of a new conducting organic-inorganic compound, NH 2 CH؍NH 2 SnI 3 , which at room temperature adopts a cubic perovskite structure. The lattice constant for