Theoretical study of the gas-phase thermolysis reaction of alkyl (ethyl, isopropyl, and tert-butyl) N,N-dimethylcarbamates and N,N-diethylcarbamates
✍ Scribed by Camilo Quijano; Rafael Notario; Jairo Quijano; Claudia Sánchez; Luis A. León; Ederley Vélez
- Book ID
- 105885614
- Publisher
- Springer
- Year
- 2003
- Tongue
- English
- Weight
- 479 KB
- Volume
- 110
- Category
- Article
- ISSN
- 1432-2234
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📜 SIMILAR VOLUMES
The rates of gas-phase elimination of N-ethyl (1), N-isopropyl (2), N-t-butyl (3) substituted 2-aminopyrazine and N-ethyl (4), N-isopropyl (5), and N-t-butyl (6) substituted 2-aminopyrimidine have been measured. The compounds undergo unimolecular first-order pyrolytic reactions. The relative rates o
The elimination kinetics of ethyl, isopropyl and tert-butyl N,N-diethylcarbamates were investigated in a static reaction vessel over the temperature range 220-400 °C and pressure range 17-160 Torr. These reactions are homogeneous, unimolecular and follow a first-order rate law. The temperature depen
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