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Gas-phase pyrolytic reactions of N-ethyl, N-isopropyl, and N-t-butyl substituted 2-aminopyrazine and 2-aminopyrimidine

✍ Scribed by Nouria A. Al-Awadi; Osman M. E. El-Dusouqui; Kamini Kaul; Hicham H. Dib

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 90 KB
Volume: 32
Category: Article
ISSN: 0538-8066
DOI: 10.1002/(sici)1097-4601(2000)32:7<403::aid-kin2>3.0.co;2-p

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✦ Synopsis

The rates of gas-phase elimination of N-ethyl (1), N-isopropyl (2), N-t-butyl (3) substituted 2-aminopyrazine and N-ethyl (4), N-isopropyl (5), and N-t-butyl (6) substituted 2-aminopyrimidine have been measured. The compounds undergo unimolecular first-order pyrolytic reactions. The relative rates of the primary : secondary : tertiary alkyl homologues at 600 K are 1 : 14.4 : 38.0 for the pyrazines and 1 : 20.8 : 162.5 for the pyrimidines, respectively. The reactivities of these compounds have been compared with those of the alkoxy analogues and with each other. Product analyses, together with the kinetic data, were used to outline a feasible pathway for the elimination reaction of the compounds under study.

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