Theoretical Study of the 1,3-Dipolar Cycloaddition Reactions of Azomethine Ylides. A DFT Study of Reaction between Trifluoromethyl Thiomethyl Azomethine Ylide and Acronitrile
β Scribed by Domingo, Luis R.
- Book ID
- 120484006
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 206 KB
- Volume
- 64
- Category
- Article
- ISSN
- 0022-3263
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AbstractΓStable bicyclic, monocyclic and aromatic azomethine ylides 1, 13 and 16 add angle-strained, electron-rich and electron-poor alkynes as well as alkenes and heterocumulenes to form 1:1-adducts in highly stereoselective 1,3-dipolar cycloadditions. Unsymmetrical dipolarophiles react in a regios
A simple and efficient method for the synthesis of novel spiropyrrolidines has been accomplished by regioselective 1,3-dipolar cycloaddition reactions of an azomethine ylide generated by thermalring opening of cis-1-cyclohexyl-2-phenyl-3-benzoyl aziridine with various (E)-3-arylidene-4-chromanones.
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