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1,3-Dipolar Cycloaddition Reactions of Stable Bicyclic and Monocyclic Azomethine Ylides: Kinetic Aspects

✍ Scribed by Kurt Elender; Peter Riebel; Andreas Weber; Jürgen Sauer

Book ID
108370840
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
110 KB
Volume
56
Category
Article
ISSN
0040-4020

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✍ Kurt Elender; Heinrich Nöth; Peter Riebel; Andreas Weber; Jürgen Sauer 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 360 KB

AbstractÐStable bicyclic, monocyclic and aromatic azomethine ylides 1, 13 and 16 add angle-strained, electron-rich and electron-poor alkynes as well as alkenes and heterocumulenes to form 1:1-adducts in highly stereoselective 1,3-dipolar cycloadditions. Unsymmetrical dipolarophiles react in a regios