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Theoretical study of substituent effects on the gas-phase stabilities of phenoxide anions

✍ Scribed by Kazuhide Nakata; Mizue Fujio; Kichisuke Nishimoto; Yuho Tsuno

Book ID
112175580
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
588 KB
Volume
26
Category
Article
ISSN
0894-3230

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Gas phase substituent effects. Stabiliti
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✍ Masaaki Hishima; Hiroki Inoue; Mizue Fujio; Yuho Tsuno πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 French βš– 290 KB

Gss-phase stabilities of 1-aryl-2,2,2-trifluoroethyl cations were determined based on chloride-transfer equilibria. The substituent effect was analyzed based on the LArSR Eq., giving a remarkably high r of 1.53 and a p of -14.6. The previous study' has shown that the substituent effect for the gas-p