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Gas phase substituent effects. Stabilities of 1-aryl-2,2,2-trifluoroethyl cations

✍ Scribed by Masaaki Hishima; Hiroki Inoue; Mizue Fujio; Yuho Tsuno

Book ID
104226645
Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
290 KB
Volume
31
Category
Article
ISSN
0040-4039

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✦ Synopsis

Gss-phase stabilities of 1-aryl-2,2,2-trifluoroethyl cations were determined based on chloride-transfer equilibria. The substituent effect was analyzed based on the LArSR Eq., giving a remarkably high r of 1.53 and a p of -14.6. The previous study' has shown that the substituent effect for the gas-phase stabilities of 1-aryl-1-(trifluoromethyl)ethyl cations can be described excellently in terms of our LArSR equation (1)2 with an r of 1.40 and a p of -14.0. aAGo = p(a" + r AZ:) (I)

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