Theoretical Study of Ring Exchange in the Borocenium Cation, [B(C 5 R 5 ) 2 ] + (R = H, Me)
β Scribed by Kwon, Ohyun; McKee, Michael L.
- Book ID
- 126930187
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 102 KB
- Volume
- 105
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
## Abstract The reaction of the vinylidene complexes [(C~5~H~5~)(CO)(NO)W=C=C(H)R] (10a: R = __t__Bu; 10b: R = Ph) with the arsaalkene __t__BuC(O)βAs=C(NMe~2~)~2~ (11) afforded the novel Ξ·^2^β1βarsaallene complexes [Ξ·^2^β{__t__BuC(O)βAs=C=C(H)R}W(CO)(NO)C~5~H~5~] (13: R = __t__Bu; 15: R = Ph). Simi
## The photolysis of [(T'-CsR,)Mn(CO),(NO)]' (RS=HZ, H4Me, MeS) was studied by Fourier transform IR spectroscopy in a low temperature 1,2-epoxyethylbenzene glass and in surface films. In each case the primary photoproduct was found to be [(~5-CsRS)Mn(CO)(NO)]'. The result of subsequent photoIysis