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π-complexes of monoanionic carborane ligand [9-(Me2S)-7,8-C2B9H10]−with [η-C5R5Fe]+(R=H, Me) and [η-C4Me4Co]+cationic fragments

✍ Scribed by A. R. Kudinov; V. I. Meshcheryakov; P. V. Petrovskii; M. I. Rybinskaya


Publisher
Springer
Year
1999
Tongue
English
Weight
209 KB
Volume
48
Category
Article
ISSN
1573-9171

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Synthesis of complexes with molybdenum-p
✍ John C. Jeffery; Mark D. Mortimer; F.Gordon A. Stone 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 924 KB

Treatment of [tram-PtH(Cl)(PEt&], in tetrahydrofuran at -30 "C, with [NEt,][Mo(=CCJ&Me-4)(CO),(q' -&B&Me,)], in the presence of TlBF,, affords the thermally labile complex [MoPt(CO),(PEt&{$-~B&(CH,C,&Me-4)Me2}]. Addition of donor molecules L [CO, PEt, or dppm (Ph2PCH,PPh2)] to the latter at low temp