𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Theoretical study of ethylene polymerization on Ziegler–Natta catalysts and on metallocene catalysts

✍ Scribed by Akinobu Shiga

Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
250 KB
Volume
146
Category
Article
ISSN
1381-1169

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Polymerization of propylene by mixed Zie
Polymerization of propylene by mixed Ziegler–Natta and metallocene catalysts
✍ Anatoli Lisovskii; Michael Shuster; Michael Gishvoliner; Gershon Lidor; Moris S. 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 126 KB 👁 2 views

The polymerization of propylene using a mixture of racemic metallocenes and Ziegler-Natta catalysts was investigated. The polypropylene was obtained as a mixture of a fine powder and beads, with the powder being absorbed partially on the beads. The relative amount of the powder can be controlled by

Ethylene polymerization with homogeneous
Ethylene polymerization with homogeneous Ziegler-Natta catalysts: theoretical study on the role of ion pairs in the polymerization mechanism
✍ Roberto Fusco; Luca Longo; Francesco Masi; Fabio Garbassi 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 420 KB 👁 1 views

## Abstract The thermodynamics of the reaction of an ethylene molecule with the Cp~2~TiCH~3~Cl/Al(CH~3~)~2~Cl system (Cp = η~5~‐C~5~H~5~), as a model for olefin polymerization with homogeneous Ziegler‐Natta catalysts, was investigated via quantum mechanical DFT calculations. The comparison of the c

Ethylene polymerization reactions with Z
Ethylene polymerization reactions with Ziegler–Natta catalysts. I. Ethylene polymerization kinetics and kinetic mechanism
✍ Y. V. Kissin; R. I. Mink; T. E. Nowlin 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 287 KB 👁 1 views

Kinetics of ethylene homopolymerization reactions and ethylene/1-hexene copolymerization reactions using a supported Ziegler-Natta catalyst was carried out over a broad range of reaction conditions. The kinetic data were analyzed using a concept of multicenter catalysis with different centers that r