1,4-Addition of Bis(iodozincio)methane t
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Mutsumi Sada; Dr. Taniyuki Furuyama; Dr. Shinsuke Komagawa; Prof. Dr. Masanobu U
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Article
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2010
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John Wiley and Sons
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English
⚖ 358 KB
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## Abstract 1,4‐Addition of bis(iodozincio)methane to simple α,β‐unsaturated ketones does not proceed well; the reaction is slightly endothermic according to DFT calculations. In the presence of chlorotrimethylsilane, the reaction proceeded efficiently to afford a silyl enol ether of β‐zinciomethyl