## Abstract 1,4‐Addition of bis(iodozincio)methane to simple α,β‐unsaturated ketones does not proceed well; the reaction is slightly endothermic according to DFT calculations. In the presence of chlorotrimethylsilane, the reaction proceeded efficiently to afford a silyl enol ether of β‐zinciomethyl
ChemInform Abstract: 1,4-Addition of Bis(iodozincio)methane to α,β-Unsaturated Ketones: Chemical and Theoretical/Computational Studies.
✍ Scribed by Mutsumi Sada; Taniyuki Furuyama; Shinsuke Komagawa; Masanobu Uchiyama; Seijiro Matsubara
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 61 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
The 1,4‐addition of bis(iodozincio)methane to α,β‐unsaturated ketones proceeds in the presence of chlorotrimethylsilane and affords silyl enol ethers of β‐zincinomethyl ketone.
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