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Theoretical studies of SN2 transition states. 1. Geometries

✍ Scribed by Wolfe, Saul; Mitchell, David John; Schlegel, H. Bernhard

Book ID
124061738
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
407 KB
Volume
103
Category
Article
ISSN
0002-7863

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Theoretical studies of SN2 transition st
Theoretical studies of SN2 transition states, the alpha effect
✍ Saul Wolfe; D.J. Mitchell; H. Bernhard Schlegel; C. Minot; O. Eisenstein πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 French βš– 301 KB

The quazitative HOMO-LVMO orbital interaction interpretation of the aZpha effect is found to be invaZid for anionic nucleophiles. In any event, gas phase SN2 reactions of HOO-and FO'O-show no evidence of the effect. The role of a hydroxylic solvent requires greater consideration as the source of pos