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Theoretical studies of photoionization in nitric oxide: Multiplet-specific spectral shapes of (5σ−1)b3II and (5σ−1) A 1II partial cross sections

✍ Scribed by M.R. Hermann; S.R. Langhoff; P.W. Langhoff


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
599 KB
Volume
109
Category
Article
ISSN
0009-2614

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✦ Synopsis


Slultipletrpecitic

calculations in static-eschange approximation are reported of (50')b 3fl and (56')A tll partialchnnnel photoionization cross sections in nitric aside. The calculated cross sections exhibit resonance peaks at significantly different kinetic energies in the two multiplet channels, clarifying the ori_tis of similar behaviors observed in recent synchrorron-radiation studies.


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Theoretical studies of photoionization i
✍ M.R. Hermann; S.R. Langhoff; T.J. Gil; P.W. Langhoff 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 764 KB

Theoretical studies are reported of vibrationally resolved (50-r) b311 (v = 0,l) and (5~~') A'JI (v = 0,l) resonant partial photoionization cross sections in nitric oxide. Calculations in vibrationally averaged, R-centroid, and Franck-Condon static-exchange approximations clarify the origins of mult