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Theoretical studies of photoionization in nitric oxide: Multiplet-specific effects in vibrationally resolved 5σ−1 resonant channels

✍ Scribed by M.R. Hermann; S.R. Langhoff; T.J. Gil; P.W. Langhoff

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 764 KB
Volume: 125
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)85168-5

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✦ Synopsis

Theoretical studies are reported of vibrationally resolved (50-r) b311 (v = 0,l) and (5~~') A'JI (v = 0,l) resonant partial photoionization cross sections in nitric oxide. Calculations in vibrationally averaged, R-centroid, and Franck-Condon static-exchange approximations clarify the origins of multiple&specific spectral shapes observed in recent cross sectional measurements.

The sensitivity of resonance-channel photoionization cross sections to internuclear separation is attributed to a well-known corresponding'dependence of o* orbital position and character on bond length.

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Theoretical studies of photoionization i

Theoretical studies of photoionization in nitric oxide: Multiplet-specific spectral shapes of (5σ−1)b3II and (5σ−1) A 1II partial cross sections

✍ M.R. Hermann; S.R. Langhoff; P.W. Langhoff 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 599 KB

## Slultipletrpecitic calculations in static-eschange approximation are reported of (50')b 3fl and (56')A tll partialchnnnel photoionization cross sections in nitric aside. The calculated cross sections exhibit resonance peaks at significantly different kinetic energies in the two multiplet channe