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Theoretical investigation on the mechanism and kinetics of the ring-opening polymerization of ε-caprolactone initiated by tin(II) alkoxides

✍ Scribed by Chanchai Sattayanon,Nawee Kungwan,Winita Punyodom…

Book ID
125440336
Publisher
Springer-Verlag
Year
2013
Tongue
English
Weight
337 KB
Volume
19
Category
Article
ISSN
1610-2940

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## Abstract Rate constants of the ring‐opening polymerization (ROP) of __ε__‐caprolactone (__ε__‐CL) by microwave heating (MH) and flash conventional heating (FCH) have been measured. The reaction is catalyzed by stannous octanoate (Sn(Oct)~2~). With a microwave power level of 400, 500, 600, 700 an

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## Abstract Summary: The synthesis of core‐shell particles with a poly(__ε__‐caprolactone) (PCL) shell and magnetite (Fe~3~O~4~) contents of between 10 wt.‐% and 41 wt.‐% proceeds by surface‐initiated ring‐opening polymerization of __ε__‐caprolactone to give surface‐immobilized oligomers with $\ove