## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Theoretical Insights into Enantioselective Catalysis: The Mechanism of the Kharasch–Sosnovsky Reaction
✍ Scribed by José Antonio Mayoral; Sergio Rodríguez-Rodríguez; Luis Salvatella
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 703 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0947-6539
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract DFT calculations on a silver‐catalysed transsiliranation reaction (silylene transfer from a silirane to an alkene) have shown the key role of a silylenesilver ion in the catalyticcycle. Although the corresponding triflate‐bound species has previously been detected by NMR and IR spectros
Reductive coupling of ketones to form alkenes, an extremely useful synthetic process in organic chemistry, is most often achieved with the aid of low-valent titanium reagents, according to the procedure developed by McMurry."] It is generally accepted that this reaction involves the intermediacy of
## Abstract Acylation of acetylcholine (ACh) catalyzed by acetylcholinesterase (AChE) has been studied using high‐level theoretical calculations on a model system that mimics the reaction center of the enzyme, and compared with uncatalyzed acylation reaction. The geometries of all the intermediates