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ChemInform Abstract: Theoretical Insights into Enantioselective Catalysis: The Mechanism of the Kharasch—Sosnovsky Reaction.

✍ Scribed by Jose Antonio Mayoral; Sergio Rodriguez-Rodriguez; Luis Salvatella

Publisher
John Wiley and Sons
Year
2009
Weight
15 KB
Volume
40
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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A Theoretical Insight into the Mechanism of the Silver-Catalysed Transsiliranation Reaction
✍ José Antonio Mayoral; Sergio Rodríguez-Rodríguez; Luis Salvatella 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 187 KB

## Abstract DFT calculations on a silver‐catalysed transsiliranation reaction (silylene transfer from a silirane to an alkene) have shown the key role of a silylenesilver ion in the catalyticcycle. Although the corresponding triflate‐bound species has previously been detected by NMR and IR spectros