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Theoretical computation of the heats of hydrogen abstraction reactions

✍ Scribed by D. Peeters; G. Leroy

Book ID
103031357
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
442 KB
Volume
246
Category
Article
ISSN
0009-2614

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The gas phase photolysis of CCl, in the presence of several alkanes has been used to obtain Arrhenius parameters for the abstraction of hydrogen atoms by the cc& radical: (4) Cc1, + RH -% CRCI, + R The following log k4 values were obtained: 2,3-Dimethylbutane C -C ~H I ~ Methy lcy clohexane log k4 1