## Abstract The kinetics and mechanisms of the dehydrochlorination of 2โchloroโ1โ phenylethane, 3โchloroโ1โphenylpropane, 4โchloroโ1โphenylbutane, 5โchloroโ1โphenylpentane, and their corresponding chloroalkanes were examined by means of electronic structure calculation using density functional theo
Theoretical calculations of product percentage yields for the thermal decomposition of 2-chloro-1,1-difluoroethane
โ Scribed by Melinda R Beaver; George L Heard; Bert E Holmes
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- French
- Weight
- 74 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
Bis(2,4-diaryl-3-thienyl) disulfide was isolated in the thermal decomposition of 2,5-diaryl-1,4-dithiin. The formation of the rearranged product as well as the kinetic data suggest strongly the valence isomerization of 2,5-diaryl-1,4-dithiin in the course of the decomposition.
A new theory of spectral thermal shifts (TS) has been developed. For the first time, by taking into account all the irreducible representations and their components in the electron-phonon interaction (EPI), all the levels and the admixtures of wavefunctions within d 3 electronic configuration, the m