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The rearranged products in thermal decomposition of 2,5-diaryl-1,4-dithiin. Evidence for valence isomerization of 1,4-dithiin system.

✍ Scribed by Keiji Kobayashi; Kiyoshi Mutai; Hayao Kobayashi

Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
246 KB
Volume
20
Category
Article
ISSN
0040-4039

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✦ Synopsis

Bis(2,4-diaryl-3-thienyl) disulfide was isolated in the thermal decomposition of 2,5-diaryl-1,4-dithiin.

The formation of the rearranged product as well as the kinetic data suggest strongly the valence isomerization of 2,5-diaryl-1,4-dithiin in the course of the decomposition.

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