Ground state atomic sulfur was generated by 193-nm laser photolysis of CS 2 precursor in Ar bath gas, in the presence of a large excess of NO 2 under pseudo-first-order conditions. Decays of S( 3 P J ) were monitored over 292-656 K and pressures of 14-535 mbar. No pressure dependence was observed, a
Theoretical calculations for the kinetics of the HN+NO reaction
β Scribed by S. Kristyan; M.C. Lin
- Book ID
- 108312638
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 104 KB
- Volume
- 297
- Category
- Article
- ISSN
- 0009-2614
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The rare cocificwn ior the rcact~on oiCF,02 with NO has been mcasurcd at 295 R m hcbum usins 3 ilow tube nmplcd by 2 rnxs spcctromurcr The KIIUC obrlmed ior this raw coeiircicnt was (17 8 f 3 6) x IO-'\* crK3 s-t and iound to bc indcpcndcnr of [Hc] over the range (6 3-16 8) x lOI cmm3. Tbls value is
The termolecular rate constant for the reaction C1 + NO, + M has been measured over the temperature range 264 to 417 K and at pressure 1 to 7 torr in a discharge flow system using atomic chlorine resonance fluorescence at 140 nm to monitor the decay of C1 in an excess of NO,. The results are ky = 9.