Theoretical and Synthetic Studies on [Zn2(η5-C5Me5)2]: Analysis of the ZnZn Bonding Interaction
✍ Scribed by Diego del Río; Agustín Galindo; Irene Resa; Ernesto Carmona
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 124 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0044-8249
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The reactions of the bis(trimethylsilyl)acetylene permethylmetallocene complexes Cp 2 M(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (1), M = Zr (2)) with H 2 O and CO 2 were studied and compared to those of the corresponding metallocene complexes Cp 2 M(L)(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (3), L = ± ; M = Zr,
## Abstract The capacity of the imido‐nitrido organometallic ligand [{Ti(η^5^‐C~5~Me~5~)(μ‐NH)}~3~(μ~3~‐N)] (1) to entrap main group metal halides MX~__n__~ has been investigated. Treatment of 1 with metal halides in toluene or dichloromethane afforded several soluble adducts [MX~__n__~(L)] (L=1) i
65% 13 16 Scheme2. Reactionsof 1 ( X ' , X 2 = O ; a ) , 8 ( X ' , X ' = N -N H -T s ; b ) , 9 ( X ' , X'=N-NNa-Ts; c, d), and 10 ( X , = H , X2=Me--S0,; f). a) Al2O3. b) MeLi, EtzO, 0°C. c) 125°C. d) hv, THF, 20°C. e) Preparative gas chromatography, Carbowax, 160°C. f) KOtBu.