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Theoretical and Experimental Investigation of the Energetics of Cis−Trans Proline Isomerization in Peptide Models

✍ Scribed by Schroeder, Olivia E.; Carper, Emily; Wind, Joshua J.; Poutsma, Jennifer L.; Etzkorn, Felicia A.; Poutsma, John C.


Book ID
125945043
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
183 KB
Volume
110
Category
Article
ISSN
1089-5639

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## Abstract The pseudoproline residue (ΨPro, L‐2,2‐dimethyl‐1,3‐thiazolidine‐4‐carboxylic acid) has been introduced into heterochiral diproline segments that have been previously shown to facilitate the formation of β‐hairpins, containing central two and three residue turns. NMR studies of the octa