Theoretical Analysis of the CH Stretching Overtone Vibration of 1,2-Dichloroethylene
β Scribed by Takahashi, Kaito; Sugawara, Michihiko; Yabushita, Satoshi
- Book ID
- 126172948
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 95 KB
- Volume
- 106
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
We have observed and analyzed the first overtone triad of the m 1 and m 7 CH stretching modes of ketene in the range of 6000-6300 cm Γ1 . The K a ΒΌ 0 components of all three bands could be assigned based on missing Q-branches and combination differences, allowing an unambiguous determination of the
Two theoretical models for the interpretation of the existing data of CH-stretching overtones' vibrational circular dichroism data are presented. The first model is based on the quantum mechanical Van Vleck contact transformation theory and is applied to the full vibrational problem, the second is b