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Redistribution and Relaxation of Vibrational Excitation of CH-Stretching Modes in 1,1-Dichloroethylene and 1,1,1-Trichloroethane

✍ Scribed by Hartl, I.; Zinth, W.


Book ID
126439764
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
12 KB
Volume
104
Category
Article
ISSN
1089-5639

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Local mode and normal mode interpretatio
✍ J.L. Duncan; I.M. Mills πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 English βš– 463 KB

The =CHI and =CD2 stretching vibrational overtones of H&-CD2 have been studied up to V= 6 and V= 3, respectively. We report their interpretation in terms of a transition from normal to local modes, involving Fermi resonance with the C-C stretching and CHz scissoring vibrations. We discuss the altern