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The ν6Band of Methyl Chloride Revisited by Fourier Transform Spectroscopy

✍ Scribed by M.-F. LeMoal; M. Margottin-Maclou; A. Valentin

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
197 KB
Volume
183
Category
Article
ISSN
0022-2852

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✦ Synopsis

The n 6 band of methyl chloride centered near 1018 cm 01 has been recorded with a precise homemade Fourier transform spectrometer. About 5400 lines of this band have been assigned. The ground state constants for both isotopomers, CH 3

35 Cl and CH 3 37 Cl, were obtained from combination differences of the wavenumbers and the upper state constants were deduced from a least-squares fit procedure which permits reproduction of the observed wavenumbers with a standard deviation of 1.1 1 10 04 cm 01 , close to the experimental uncertainty.

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