𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Rovibrational Constants for the ν6 and 2ν9 Bands of HCOOD by Fourier Transform Infrared Spectroscopy

✍ Scribed by T.L. Tan; K.L. Goh; P.P. Ong; H.H. Teo

Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
103 KB
Volume
198
Category
Article
ISSN
0022-2852

No coin nor oath required. For personal study only.

✦ Synopsis

The Fourier transform infrared spectrum of the 6 and 2 9 bands of deuterated formic acid (HCOOD) was recorded with an apodized resolution of 0.004 cm Ϫ1 in the frequency range of 930 -1040 cm Ϫ1 . These two bands with band centers 40 cm Ϫ1 apart were mutually coupled by Coriolis and Fermi interactions. By fitting a total of 1076 infrared transitions of both 6 and 2 9 with a standard deviation of 0.00075 cm Ϫ1 using a Watson's A-reduced Hamiltonian in the I r representation with the inclusion of c-type Coriolis and a Fermi-resonance term, two sets of rovibrational constants for v 6 ϭ 1, and v 9 ϭ 2 states were derived for the first time. Both 6 and 2 9 bands are A type with band centers at 972.8520 Ϯ 0.0001 and 1011.6766 Ϯ 0.0001 cm Ϫ1 , respectively.

📜 SIMILAR VOLUMES

Improved Rovibrational Constants for the
Improved Rovibrational Constants for the ν3 Infrared Band of HCOOD
✍ K.L. Goh; P.P. Ong; H.H. Teo; T.L. Tan 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 59 KB

Since formic acid (HCOOH) is an important constituent in interstellar space (1), it is worthwhile to study HCOOD to determine rovibrational constants that would provide a reliable calculation of the spectra of HCOOD. The present work provides improved spectroscopic constants for the 3 band of HCOOD

Fourier Transform Infrared Spectra of Fo
Fourier Transform Infrared Spectra of Formaldoxime: The ν7, ν9, ν11, ν12, and 2ν12Bands
✍ R.A. Bannai; G. Duxbury; G. Ritchie; S. Klee 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 364 KB

A first full rotational analysis of high-resolution gas-phase spectra of the lowest frequency fundamental bands, n 9 and n 12 , of formaldoxime, CH 2 NOH, has been completed. In addition the weak n 7 fundamental has been analyzed at medium resolution, and the complex structure of the bands in the n

Fourier Transform Infrared Spectra of CH
Fourier Transform Infrared Spectra of CH2DF: The ν5 and ν6 Bands
✍ I.A. Atkinson; M.M. Law 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 111 KB

Results of a high-resolution infrared study of the spectroscopy of monodeuterated methyl fluoride, CH 2 DF, are reported for the first time. Spectra ranging from 500 to 3300 cm -1 have been obtained and cover all the fundamental bands at resolutions down to 0.005 cm -1 . The two lowest energy fundam

Fourier Transform Infrared Spectrum of C
Fourier Transform Infrared Spectrum of ClCN: Analysis of the ν1 + ν3, 2ν2 + ν3, and Associated Hot Bands
✍ A. Saouli; I. Dubois; J.F. Blavier; H. Bredohl; G. Blanquet; C. Meyer; F. Meyer 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 327 KB

The Fourier transform spectra of \(\mathrm{CICN}\) have been recorded between 2860 to \(3030 \mathrm{~cm}^{-1}\) with a resolution of \(0.0026 \mathrm{~cm}^{-1}\). The \(\nu_{1}+\nu_{3}\) and \(2 \nu_{2}+\nu_{3}\) bands and the associated hot bands have been analyzed. A band-by-band analysis has bee

High-Resolution Infrared Fourier-Transfo
High-Resolution Infrared Fourier-Transform Spectroscopy and Rotational Constants of the ν4Band of BrNO2
✍ J. Orphal; A. Frenzel; H. Grothe; B. Redlich; D. Scheffler; H. Willner; C. Zetzs 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 148 KB

For the first time, high-resolution infrared gas-phase absorption spectra of the BrNO 2 molecule were recorded using a Fourier-transform spectrometer. In this paper, the 4 bands of the 79 BrNO 2 and 81 BrNO 2 isotopomers around 1670 cm Ϫ1 are investigated. Although the spectra are highly congested,

New High-Resolution Analysis of the ν3,
New High-Resolution Analysis of the ν3, ν4, and ν6Bands of D2CO Measured by Fourier Transform Spectroscopy
✍ A. Perrin; J.-M. Flaud; A. Predoi-Cross; M. Winnewisser; B.P. Winnewisser; G. Me 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 269 KB

A reanalysis of the n 3 , n 4 , and n 6 interacting bands of D 2 CO has been carried out in the region 850-1250 cm 01 using high-resolution Fourier transform spectra recorded at Giessen. As compared to the previous study of these bands (1987, K. Nakagawa, R. H. Schwendeman, and J. W. C. Johns, J. Mo