Fourier Transform Infrared Spectrum of ClCN: Analysis of the ν1 + ν3, 2ν2 + ν3, and Associated Hot Bands

✍ Scribed by A. Saouli; I. Dubois; J.F. Blavier; H. Bredohl; G. Blanquet; C. Meyer; F. Meyer

• Publisher: Elsevier Science
• Year: 1994
• Tongue: English
• Weight: 327 KB
• Volume: 165
• Category: Article
• ISSN: 0022-2852
• DOI: 10.1006/jmsp.1994.1138

✦ Synopsis

The Fourier transform spectra of (\mathrm{CICN}) have been recorded between 2860 to (3030 \mathrm{~cm}^{-1}) with a resolution of (0.0026 \mathrm{~cm}^{-1}). The (\nu_{1}+\nu_{3}) and (2 \nu_{2}+\nu_{3}) bands and the associated hot bands have been analyzed. A band-by-band analysis has been performed and also, for the first time, a global analysis has been made including all available data for the rotational and rovibrational energies of both ({ }^{35} \mathrm{Cl}^{12} \mathrm{C}^{14} \mathrm{~N}) and ({ }^{37} \mathrm{Cl}^{12} \mathrm{C}^{14} \mathrm{~N}) isotopomers. The (2 \nu_{2}+v_{3}) band has been analyzed for the less abundant isotopic species ({ }^{35} \mathrm{Cl}^{13} \mathrm{C}^{14} \mathrm{~N}). ({ }^{35} \mathrm{Cl}^{12} \mathrm{C}^{15} \mathrm{~N}), and ({ }^{37} \mathrm{Cl}^{13} \mathrm{C}^{14} \mathrm{~N}). (c) 1994 Academic Press. Inc.