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The ν6, ν7, ν8, and ν10 Bands of HO2NO2

✍ Scribed by R.R. Friedl; R.D. May; G. Duxbury

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
548 KB
Volume
165
Category
Article
ISSN
0022-2852

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✦ Synopsis

Two new fundamental vibration-rotation bands have been observed for (\mathrm{HO}{2} \mathrm{NO}{2}) and assigned. They are (\nu_{7}) at (648 \mathrm{~cm}^{-1}) and (\nu_{8}) at (466 \mathrm{~cm}^{-1}). On the basis of these assignments the previously observed bands at (722,801.5), and (919 \mathrm{~cm}^{-1}) are assigned to (\nu_{10}, \nu_{7}+\nu_{12}), and (2 \nu_{8}), respectively. A partial rotational analysis of the atmospherically relevant (v_{6}) band has been carried out, and the effects of tunneling, Coriolis interactions, and hot bands on the rotational structure have been characterized. The band origin derived from this analysis is (802.54_{3} \mathrm{~cm}^{-1}).C 1994 Academic Press, Inc.

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