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The [(μ3-WSe4)3(μ3-Se)2 (Cu3)2]4− Anion, an Inorganic Cluster with a Pin wheel Shape

✍ Scribed by Christopher C. Christuk; Dr. Mohammad A. Ansari; Prof. Dr. James A. Ibers


Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
278 KB
Volume
31
Category
Article
ISSN
0044-8249

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A novel lead(II) cluster [Pb 7 (µ 3 -O)(µ 4 -O)(µ 3 -OMe) 4 (µ 2 -I) 4 ]I 2 (1) has been isolated from the reaction mixture of PbI 2 and pyrazine in DMF/MeOH solvent with a reasonable yield (46%). The X-ray crystallography shows that 1 exhibits a novel unprecedented cage structure with centered µ 3