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The β-d-GalpNAc-(1 → 3)-d-Galp linkage through the oxazoline glycosylation method

✍ Scribed by Diego Colombo; Luigi Panza; Fiamma Ronchetti

Book ID
102991731
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
250 KB
Volume
276
Category
Article
ISSN
0008-6215

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Oligosaccharides related to tumor-associ
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## Synthesis of the Propyl Glycosides of the TrisaccharideP-D-Galp-(l+3)-P-D-GalpNAc-(1+3)-a-D-Galp and of the Tetrasaccharide E-L-Fuc~-(~+~)-/?-D-Galp-(1+3)-j?-~-GalpNAc-(1+3)-a-D-Galp, Components of a Tumor Antigen ') part 2: [I].

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Mucin-type O-glycopeptides containing the &D-Gab-( l-+3)-o-G@NAc disaccharide core unit, which is also the T-antigenic determinant, were synthesized from o-galactose, 2-azido-%deoxy-o-galactose, 2-azido-2-deoxylactose, and L-serine precursors by applying the trichloroacetimidate method. Thus, fi-~-G