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The α-effect of oximate ions and solvent effect in the transfer of the toluenesulfonyl group in aqueous dimethylsulfoxide

✍ Scribed by Yu. S. Simanenko; T. M. Zubareva; I. P. Suprun; T. M. Prokop'eva; A. F. Popov; E. A. Karpichev

Book ID
110544344
Publisher
Springer
Year
2000
Tongue
English
Weight
293 KB
Volume
36
Category
Article
ISSN
0040-5760

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Pitfalls in the determination of the α-effect by a two-point analysis. The effect of solvent on the α-effect.
✍ Shmaryahu Hoz; Erwin Buncel 📂 Article 📅 1984 🏛 Elsevier Science 🌐 French ⚖ 226 KB

The methodology for evaluation of the a-effect is examined and it is shown that the two-point analysis method is generally of limited value. This leads to a re-examination of the effect of solvent on the a-effect. The a-effect, defined as the positive deviation of an a-nucleophilo (e.g., HOO-, NH\