The effect of solvent on the α-effect: Abnormal nucleophilic reactivity of substituted acetophenone oximate anions in aqueous DMSO
✍ Scribed by Ik-Hwan Um; Su-Jin Oh; Dong-Sook Kwon
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 206 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Kinetic studies are reported for the reactions with aniline in benzene of a series of X‐phenyl 2,4,6‐trinitrophenyl ethers [X = H; 2‐, 3‐, 4‐CH~3~; 2,4‐, or 2,6‐(CH~3~)~2~] a–f, and the results compared with those of the corresponding nitro derivatives. In the methyl series, kinetic dat
The kinetics of the reaction between l-chloro-2,4-dinitrobenzene and piperidine was studied in several completely non-aqueous binary solvent mixtures where the preferential solvation is the rule at 15,Z and 40 "C. The reaction was chosen as the simplest example of aromatic nucleophilic substitution