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The zirconocene induced coupling of benzyne with nitriles: Synthesis, structure and reactions of novel azametallacyclopentenes

✍ Scribed by Stephen L. Buchwald; Ann Sayers; Brett T. Watson; John C. Dewan

Publisher: Elsevier Science
Year: 1987
Tongue: French
Weight: 230 KB
Volume: 28
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)95483-2

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✦ Synopsis

A series of novel azazirconacyclopentenes have been prepared by the thermolysis of diphenylzirconocene in the presence of one equivalent of a wide variety of nitriles. An X-ray crystal structure shows these metallacycles to be dimeric in the solid state. 8.

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