The Reaction of Tetramesityldisilene with As4: Synthesis and Structure of a Novel Arsenic–Silicon Tricyclic Ring System
✍ Scribed by Dr. Robin P. Tan; Nadia M. Comerlato; Dr. Douglas R. Powell; Prof. Robert West
- Publisher
- John Wiley and Sons
- Year
- 1992
- Tongue
- English
- Weight
- 256 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0044-8249
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Starting from siloxycyclopropyl-substituted dimethyl derivatives 11, 12, 13, cycloeicosanone derivative 16, cyclotetradecanone derivative 19 and cyclononane malonates 1 and 2 a chain elongation was performed to give new malonates 8, 9, 10, and 18 in reasonable overall yield. derivative 22 (together
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For example. the 'H NMR spectrum of 3 in [DJbenzene contains sharp signals and, in particular, a downfield NH-singlet at 6=8.83 that is independent of concentration; the corresponding NH-singlet in model (nondimeric) glycolurils is at 6 -5.0 in [DJbenzene. The FTIR spectrum of 3 (benzene, 2 x I @ -1