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ChemInform Abstract: A Repetitive Approach to the Synthesis of Medium and Large Ring Compounds with a Ring-Opening/Ring-Closure Cascade Reaction of Siloxycyclopropane Derivatives as Crucial Step.

✍ Scribed by A. ULLMANN; H.-U. REISSIG; O. RADEMACHER


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
30
Category
Article
ISSN
0931-7597

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A Repetitive Approach to the Synthesis o
✍ Astrid Ullmann; Hans-Ulrich Reißig; Otto Rademacher πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 379 KB πŸ‘ 2 views

Starting from siloxycyclopropyl-substituted dimethyl derivatives 11, 12, 13, cycloeicosanone derivative 16, cyclotetradecanone derivative 19 and cyclononane malonates 1 and 2 a chain elongation was performed to give new malonates 8, 9, 10, and 18 in reasonable overall yield. derivative 22 (together