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The x-ray photoelectron spectra of copper(I) and copper(II) carboxylates

โœ Scribed by D.A Edwards

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
264 KB
Volume
18
Category
Article
ISSN
0020-1693

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โœฆ Synopsis

The X-ray photoelectron spectra of the anhydrous copper(I) and copper(U) carboxylates Cu(O,CR), (R = Me, Et, Pr", Ph; n = 1 and 2), have been investigated and the copper 2p,,, and 2~~~~ and carbon 1s binding energies measured. An apparent correlation of copper 2p binding energies with metal oxidation state has been found. The copper 2p peak widths are much broader for the copper(H) carboxylates than for the copper(I)

carboxylates, a feature attributed to multiplet splittings. Intense satellite peaks are observed only for the copper compounds.

Copper nbutyrate shows evidence of X-ray photoreduction to copper(I).

๐Ÿ“œ SIMILAR VOLUMES

X-ray photoelectron spectroscopy of copp
X-ray photoelectron spectroscopy of copper(II), copper(I), and mixed valence systems
โœ Heinz Rupp; Ulrich Weser ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science โš– 985 KB

X-ray photoelectron spectroscopy using copper( copper(I) and the mixed valence Cu(II)/Cu(i) compounds was empIoyed as a means of studying electron transfer reactions in copper proteins\_ The X-ray photoelectron spectra of copper(i1) compounds display characteristic satellites of both variable sire a