The x-ray crystal structures of the oxo-osmium complexes, OsO2(OH)2phen (1) and Os2O6py4(2)
β Scribed by Anita M. R. Galas; Michael B. Hursthouse; E. J. Behrman; W. R. Midden; G. Green; William P. Griffith
- Publisher
- Springer
- Year
- 1981
- Tongue
- English
- Weight
- 191 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0340-4285
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π SIMILAR VOLUMES
Dark blue plate-like crystals of [Cu 2 (phen) 2 (H 2 O) 2 (OH) 2 ](HCO 3 ) 2 Β΄6 H 2 O were obtained from a CH 3 OHΒ±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), sebacic acid and Na 2 CO 3 . The crystal structure (triclinic, P 1 (no. 2), a = 8.118(1), b = 9.624(1), c = 10.536(1) A Γ
The crystal and molecular structures of [Mn(phen)-(OHz)C13] (1) and [Mn(acac)2(OHE)/]C104"2H20 (2) were determined. A comparison is made of the Jahn-Teller distortion in these compounds with those observed in other manganese(III) complexes with monodentate axial ligands.