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The water structure around the chloride ion in aqueous polyethylene oxide solutions

✍ Scribed by A.C. Barnes; J.E. Enderby; J. Breen; J.C. Leyte

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
307 KB
Volume
142
Category
Article
ISSN
0009-2614

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✦ Synopsis

Neutron diffraction and nuclear magnetic relaxation yield complementary information on the interaction of ions and water molecules in solution. In the present study the two techniques are used to investigate the influence of poly( ethyleneoxide) on the Cl-hydration sphere. It is concluded that the important effect of PEO on the "Cl relaxation rate is due to the occurrence of a long correlation time rather than structural changes.

πŸ“œ SIMILAR VOLUMES

The structure around the perchlorate ion
The structure around the perchlorate ion in concentrated aqueous solutions
✍ G.W. Neilson; D. SchiΓΆberg; W.A.P. Luck πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 English βš– 326 KB

A nrutr~n dirrrxlion swdy has bsrn canicd out on o 3.15 molal solution or NaClO, in hcay u';l~cr. in which the firsI-ordsr diKerace method of isolopic subsrilution was applied 10 chlorine BIO~S or the Cloy iop. The rcsul~s show thal (a) the in~ramolaular separaion or Cl-0 is 1.43 kO.02 i in good agr