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The structure around the perchlorate ion in concentrated aqueous solutions

✍ Scribed by G.W. Neilson; D. Schiöberg; W.A.P. Luck

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
326 KB
Volume
122
Category
Article
ISSN
0009-2614

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✦ Synopsis

A nrutr~n dirrrxlion swdy has bsrn canicd out on o 3.15 molal solution or NaClO, in hcay u';l~cr. in which the firsI-ordsr diKerace method of isolopic subsrilution was applied 10 chlorine BIO~S or the Cloy iop. The rcsul~s show thal (a) the in~ramolaular separaion or Cl-0 is 1.43 kO.02 i in good agreemem with X-ray diffraction resul& from single-cry-slal smdies. (b) there are between four and five nearesl-neighbour deulerium a~orrw in the range 2.4 Q r c 3.2 ,k and (c) the ClOT -warer coordinaGon is less well defined than that Tar Cl--wawr. bul similar IO Ihal for the NO, -waler snucwre.

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