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The visible spectrum of gaseous OBrO

✍ Scribed by O.V. Rattigan; R.L. Jones; R.A. Cox

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 480 KB
Volume: 230
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(94)01129-x

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✦ Synopsis

A new visible absorption spectrum arising from a gaseous transient species in the bromine sensitized decomposition of ozone has been observed. The spectrum shows a series of absorption bands from 400-600 nm superimposed on a continuum, with a maximum absorption near 505 nm and is attributed to the symmetrical bromine oxide, OBrO, possibly formed from the reaction of BrO with 03. The implications for the partitioning of BrQ, in the atmosphere are briefly discussed.

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