The Vilsmeier Reaction of Non-Aromatic Compounds
β Scribed by Gurnos Jones; Stephen P. Stanforth
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 55 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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Reactions of hydridophosphorane 3 with Vilsmeier reagents, HCONR 1 R 2 /POCl 3 , afford novel N,N-disubstituted amino bisphosphoranyl methanes4. The formation of 4 might occur via the intermediate 5, which then reacts further with excess 3.