## A careful analysis of the Raman spectra of the M x [M(CN) 6 ] y Prussian blue species has enabled a general model for the interpretation of the ฮฝ(CN) vibrational spectra. The spectral patterns are derived from those of the metal ions with local O h symmetry. Two limiting models are discussed. A
The Vibrational Spectra of the Cyanide Ligand Revisited: Double Bridging Cyanides
โ Scribed by Sidney F. A. Kettle; Eliano Diana; Edoardo M. C. Marchese; Enrico Boccaleri; Gianluca Croce; Tianlu Sheng; Pier Luigi Stanghellini
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 342 KB
- Volume
- 2010
- Category
- Article
- ISSN
- 1434-1948
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๐ SIMILAR VOLUMES
The u, + vi combination band ofthe hydrogen cyanide dimer has been observed under sub-Doppler resolution conditions. This mode corresponds to the simultaneous excitation of one quantum in both the "free" C-H stretch and the vt, bending mode of the dimer. When combined with previous work on the Y, fu
The structure of the recently prepared formyl cyanide molecule has been determined by ab initio calculations up to the level of split valence plus polarization with inclusion of electron correlation (6\_31G\*MP3). The 6-31G\*MP3 geometry is: r,(CN) = 1.160, r.(C-C) = 1.476, r,(CO)= 1.207, r,(CH)= 1.
## Abstract Review: ca. 80 refs.