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The intermolecular bending vibrations of the hydrogen cyanide dimer

✍ Scribed by K.W. Jucks; R.E. Miller

Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 438 KB
Volume: 147
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(88)85072-3

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✦ Synopsis

The u, + vi combination band ofthe hydrogen cyanide dimer has been observed under sub-Doppler resolution conditions. This mode corresponds to the simultaneous excitation of one quantum in both the "free" C-H stretch and the vt, bending mode of the dimer. When combined with previous work on the Y, fundamental and v, + ui -vh hot bands of the dimer, the bending frequency can be determined in both the ground (40.7511 cm-') and excited (40.5520 cm-') intramolecular vibrational states.

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