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The vibrational analysis of some oxamide complexes

✍ Scribed by Hermann O. Desseyn; Walter van Riel; Laurent van Haverbeke

Publisher
Springer
Year
1980
Tongue
English
Weight
563 KB
Volume
5
Category
Article
ISSN
0340-4285

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The vibrational spectra, both i.r. and Raman, of some N-monosubstituted oxamide complexes with Pd(ll) and their deuterated derivatives are reported, using ligands which have the general form NHzCOCONHR where R = H, CHa, CH2CH3, CHzCHzCH3, NH2, CH2CH2NH2 or CH2CH2OH. The article also reports on the t

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## With dithiooxamides, Zn(II) in acid media forms distorted tetrahedral complexes, which behave as non-electrolytes. The ligands act as bidentates with S, S coordination. A thorough vibrational analysis has been performed for the Zn(CH,NHCSCSNHCH,)X, (X =Cl, Br, I) and for the Zn[(CH,),NCSCSN(