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The use of the dropping mercury electrode to determine adsorption of organic substances—I

✍ Scribed by S.G. Meibuhr

Publisher
Elsevier Science
Year
1965
Tongue
English
Weight
554 KB
Volume
10
Category
Article
ISSN
0013-4686

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📜 SIMILAR VOLUMES

General regularities in the adsorption o
General regularities in the adsorption of organic substances on a mercury electrode
✍ B.B. Damaskin; G.A. Tedoradze 📂 Article 📅 1965 🏛 Elsevier Science 🌐 English ⚖ 987 KB

It is shown that if the shape of the adsorption isotherm does not depend on the electrode potential q and the double layer capacitance C decreases to a certain limiting value with increasing concentration of the organic substance, the energy of adsorption is a quadratic function of p. In this case,

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m-Nitrophenol is adsorbed at the dme, and lowers the double-layer capacitance, at potentials more positive than its reduction potential. At that potential, a differential-capacitance peak appears that is partly faradaic in origin and partly due to the "desorption" (through reduction) of the m-nitrop

Adsorption of organic substances at the
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✍ J.I. Japaridze; N.A. Abuladze; Sh.S. Japaridze; A. De Battisti; S. Trasatti 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 673 KB

The adsorption of normal aliphatic alcohols on a polarized Hg electrode from solutions in ethylene glycol has been investigated by capacity measurements. The experimental data have been processed in terms of the Frumkin-Damaskin theory. Results have shown that the adsorption of alcohols (from hexano